Product ID:MANNITOL, M1120, M1128, MA165, MA170; CODE M3410
MSDS Date:09/26/1997
FSC:NIIN:Submitter:N EN
Status Code:A
MSDS Number: CKVGC

Emergency Phone: (310) 516-8000

Info Phone: 310-516-8000

Preparer: E. BRULL

Cage: 63415

Telephone: (310) 516-8000

Cage: TO829

MANNITOL. (C6H1406)

CAS: 69-65-8

RTECS: OP2060000

LD50 LC50 Mixture:ORAL TOXICITY (LD50): 13500 MG/KG (RAT).
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: SLIGHTLY DANGEROUS TO DANGEROUS
IN CASE OF INGESTION. VERY SLIGHTLY TO SLIGHTLY DANGEROUS IN CASE
OF SKIN OR EYE CONTACT (IRRITANT), AND INHALATION. CHRONIC: THERE
IS NO KNOWN EFFECT FROM CHRON IC EXPOSURE TO THIS PRODUCT.
CARCINOGENIC EFFECTS, MUTAGENIC EFFECTS AND TERATOGENIC EFFECTS:
NOT AVAILABLE. TOXICITY OF PRODUCT TO REPRODUCTIVE SYSTEM: NOT
AVAILABLE.
Medical Cond Aggravated by Exposure:REPEATED OR PROLONGED EXPOSURE IS
NOT KNOWN TO AGGRAVATE MEDICAL CONDITION.

First Aid:EYE CONT: IMMED FLUSH EYES W/RUNNING WATER FOR AT LEAST 15
MINS, KEEPING EYELIDS OPEN. COLD WATER MAY BE USED. SKIN CONT: IF
CHEM GOT ONTO CLOTHED PORTION OF BODY, REMOVE CONTAM CLTHG AS
QUICKLY AS PO SS, PROT YOUR OWN HANDS & BODY. PLACE VICTIM UNDER
DELUGE SHOWER. IF CHEM TOUCHES EXPOS SKIN, THOROUGHLY WASH CONTAM
SKIN W/RUNNING WATER & NON-ABRASIVE SOAP. BE PARTICULARLY CAREFUL
TO CLEAN FOLDS, C REVICES, CREASES, & GROIN. COLD WATER MAY BE
USED. COVER IRRIT SKIN W/EMOLIENT. IF IRRIT PERSISTS, SEEK MED
ATTN. WASH CONTM CLTHG BEFORE REUSING. SERIOUS SKIN CONT: NO ADDNL
INFO. INHAL: ALLOW VICTI M TO REST IN WELL VENT (OTHER INFO).

Flash Point:NOT AVAILABLE.
Autoignition Temp:=460.C, 860.F
Lower Limits:NOT AVAILABL
Upper Limits:NOT AVAILABL
Extinguishing Media:SMALL FIRE: USE DRY CHEMICALS, CO2, WATER SPRAY, OR
FOAM. LARGE FIRE: USE WATER SPRAY, FOG OR FOAM. DO NOT USE WATER
JET.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . PRODUCTS OF COMBUSTION: CARBON OXIDES (CO, CO2).
FLAMMABILITY OF THE PRODUCT: COMBUSTIBLE.
Unusual Fire/Explosion Hazard:NO SPECIFIC INFORMATION IS AVAILABLE IN
DATABASE REGARDING FLAMMABILITY OR RISKS OF EXPLOSION OF PRODUCT IN
PRESENCE OF VARIOUS MATERIALS. RISKS OF EXPLOSION OF PRODUCT IN
PRESENCE OF MECHANICAL IMPAC T OR STATIC DISCHARGE: NOT AVAILABLE.
SPECIAL REMARKS ON FIRE & EXPLOSION HAZARDS: NO ADDITIONAL REMARKS.

Spill Release Procedures:SM SPILL: USE APPROP TOOLS TO PUT SPILLED
SOLID IN A CONVENIENT WASTE DISP CNTNR. FINISH CLEANING BY
SPREADING WATER ON CONTAM SURFACE & DISPOSE OF ACCORD TO LOCAL &
REGIONAL AUTHORITY REQ. LRG SPILL: DATABASE CONTAINS NO ADDNL INFO
IN CASE OF A SPILL &/OR LEAK OF PROD. USE A SHOVEL TO PUT MATL IN
CONVENIENT WASTE DISP CNTNR. FINISH CLEANING BY SPREADING WATER ON
CONTAM SURF & ALLOW (WASTE DISP).

Handling and Storage Precautions:KEEP AWAY FROM HEAT & SOURCES OF
IGNITION. DO NOT BREATH DUST. KEEP CONTAINER DRY, IN COOL PLACE,
TIGHTLY CLOSED. GROUND ALL EQUIPMENT CONTAINING MATERIAL. KEEP IN
A COOL, WELL-VENTILATED PLACE. COMB UST MATERIALS SHOULD BE STORED
AWAY FROM EXTREME HEAT & AWAY FROM STRONG OXIDIZING AGENTS.
Other Precautions:EMPTY CONTAINERS POSE A FIRE RISK. EVAPORATE RESIDE
UNDER A FUME HOOD. GROUND ALL EQUIPMENT CONTAINING MATERIAL.

Respiratory Protection:A NIOSH APPROVED RESPIRATOR APPROPRIATE FOR THE
EXPOSURE OF CONCERN .
Ventilation:USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER
ENGINEERING CONTROLS TO KEEP AIRBORNE LEVELS BELOW RECOMMENDED
EXPOS LIMITS. (SUPP SFTY & HLTH).
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEMICAL SAFETY GOGGLES AND FULL
FACESHIELD .
Other Protective Equipment:EYEWASH & DELUGE SHOWER METING ANSI DESIGN
CRITERIA . LAB COAT.
Work Hygienic Practices:WASH CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
VENTILATION: IF USER OPERATIONS GENERATE DUST, FUME OR MIST, USE
VENTILATION TO KEEP EXPOS TO AIRBORNE CONTAMS BELOW EXPOS LIMIT.
EXPOSURE LIMITS: NOT AVAILABLE.

Boiling Pt:B.P. Text:DECOMPOSES.
Melt/Freeze Pt:=166.C, 330.8F
Vapor Pres:NOT AVAILABLE.
Vapor Density:NOT AVAIL.
Spec Gravity:1.52 (WATER=1).
pH:NOT AVAILABLE.
Solubility in Water:SOLUBLE IN COLD WATER.
Appearance and Odor:SOLID. COLOR, ODOR, TASTE, CRITICAL TEMPERATURE,
VOLATILITY: NOT AVAILABLE.

Stability Indicator/Materials to Avoid:YES
NO SPECIFIC INFORMATION IS AVAILABLE IN DATABASE REGARDING REACTIVITY
OF MATERIAL IN PRESENCE OF VARIOUS OTHER MATERIALS. SPECIAL REMARKS
ON REACTIVITY: NO ADDITIONAL REMARK.
Stability Condition to Avoid:INSTABILITY TEMPERATURE: NOT AVAIL.
CONDITIONS OF INSTABILITY: NO ADDITIONAL REMARK. CORROSIVITY:
NON-CORROSIVE IN PRESENCE OF GLASS. SPECIAL REMARKS CORROSIVITY:
NO ADDTL REMARK.

Waste Disposal Methods:DISPOSE IN ACCORDANCE W/APPLICABLE FEDERA, STATE
AND LOCAL REGULATIONS . RECYCLE TO PROCESS, IF POSS. CONSULT LOCAL
OR REGIONAL AUTH. SPILL/RELEASE: TO EVACUATE THRU SANITARY SYSTEM.
PPE IN CAS E OF LG SPILL: SPLASH GOGGLES, FULL SUIT, BOOTS, GLOVES.
SUGGESTED PROT CLOTHES MAY NOT BE SUFFICIEN T. CONSULT A SPECIALIST
BEFORE HANDLING PRODUCT.

Toxicological Information:TOXICITY TO ANIMALS: ACUTE ORAL TOXICITY
(LD50): 13500 MG/KG (RAT). SPECIAL REMARKS ON TOXICITY TO ANIMALS,
CHRONIC EFFECTS ON HUMANS, AND OTHER TOXIC EFFECTS ON HUMANS: NO
ADDITIONAL REMARKS. TOXIC OLOGICAL DATA ON INGREDIENTS: NOT
APPLICABLE. TOXICITY OF THE PRODUCT TO THE REPRODUCTIVE SYSTEM: NOT
AVAILABLE. CARCINOGENIC EFFECTS: NOT AVAILABLE. MUTAGENIC EFFECTS:
NOT AVAILABLE. TERATOGENIC EFF ECTS: NOT AVAILABLE.
PHYSICAL/CHEMICAL: ODOR THRESHOLD, WATER/OIL DIST. COEFF.,
IONICITY: NOT AVAILABLE. DISPERSION PROPERTIES: SEE SOLUBILITY IN
WATER.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:ECOTOXICITY, BOD5 AND COD: NOT AVAILABLE. PRODUCTS OF
BIODEGRADATION: CARBON OXIDES (CO, CO2). TOXICITY OF PRODUCTS OF
BIODEGRADATION: THE PRODUCTS OF DEGRADATION ARE MORE TOXIC. SPECIAL
REMARKS ON PR ODUCTS OF BIODEGRADATION: NO ADDITIONAL REMARK.

Transport Information:DOT CLASSIFICATION: NOT A DOT CONTROLLED MATERIAL
(UNITED STATES). IDENTIFICATION: NOT APPLICABLE (PIN AND PG).
SPECIAL PROVISIONS FOR TRANSPORT: NOT APPLICABLE. D.O.T.

Federal Regulatory Information:THE FOLLOWING PRODUCT IS LISTED ON TSCA:
MANNITOL. OTHER REGULATIONS: OUR DATABASE CONTAINS NO SPECIAL
CONSIDERATIONS ON THE PRODUCT. OTHER CLASSIFICATION: NOT
CONTROLLED UNDER WHMIS (CANADA). NOT CO NTROLLED UNDER DSCL
(EUROPE).
State Regulatory Information:CALIFORNIA PROPOSITION 65 WARNINGS:
WARNING: THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO STATE OF
CALIFORNIA TO CAUSE CANCER. CHEMICAL INGREDIENT REQUIRING THIS
WARNING: NONE. WARNING: THIS PRODUCT CON TAINS A CHEMICAL KNOWN TO
STATE OF CALIFORNIA TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE
HARM. CHEMICAL REQUIRING THIS WARNING: NONE. OTHER SPECIAL
CONSIDERATIONS: NO ADDITIONAL REMARK. REFERENCES: NOT AVAILABLE.